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Magnetic properties coupled with sortable silt are investigated for Holocene marine sedimentary sequences located in the subpolar North Altantic, in the Charlie– Gibbs fracture zone (53°N) and in central (57°N) and southern Gardar drift (59°N). All the cores are located at water depths bathed by the Iceland–Scotland Overflow Water, mixed at the southernmost locality with southern sourced water masses. The goal of the multi-proxy study is the changes in the dynamics and the properties of bottom water mass during Holocene. After checking that the magnetic minerals is magnetite of uniform grain size, the low field magnetic susceptibility is used as a magnetic concentration parameter and as a tracer of the transport efficiency by the bottom current from the northern basaltic-derived source. The mean sortable silt size is used as a tracer of bottom current strength whatever the detrital source.

We develop and implement a new method to take into account the impact of waves into the 3-D circulation model SYMPHONIE (Marsaleix et al., 2008, 2009a) following the simplified equations of Bennis et al. (2011) which use glm2z-RANS theory (Ardhuin et al., 2008c). These adiabatic equations are completed by additional parameterizations of wave breaking, bottom friction and wave-enhanced vertical mixing, making the forcing valid from the surf zone through to the open ocean. The wave forcing is performed by wave generation and propagation models WAVEWATCH III® (Tolman, 2008, 2009; Ardhuin et al., 2010) and SWAN (Booij et al., 1999). The model is tested and compared with other models for a plane beach test case, previously tested by Haas and Warner (2009)and Uchiyama et al. (2010). A comparison is also made with the laboratory measurements of Haller et al. (2002) of a barred beach with channels. Results fit with previous simulations performed by other models and with available observational data. Finally, a realistic case is simulated with energetic waves travelling over a coast of the Gulf of Lion (in the northwest of the Mediterranean Sea) for which currents are available at different depths as well as an accurate bathymetric database of the 0–10 m depth range. A grid nesting approach is used to account for the different forcings acting at different spatial scales. The simulation coupling the effects of waves and currents is successful to reproduce the powerful northward littoral drift in the 0–15 m depth zone. More precisely, two distinct cases are identified: When waves have a normal angle of incidence with the coast, they are responsible for complex circulation cells and rip currents in the surf zone, and when they travel obliquely, they generate a northward littoral drift. These features are more complicated than in the test cases, due to the complex bathymetry and the consideration of wind and non-stationary processes. Wave impacts in the inner shelf are less visible since wind and regional circulation seem to be the predominant forcings. Besides, a discrepancy between model and observations is noted at that scale, possibly linked to an underestimation of the wind stress. This three-dimensional method allows a good representation of vertical current profiles and permits the calculation of the shear stress associated with waves and currents. Future work will focus on the combination with a sediment transport model.

We present a new parameterisation that relates surface mass balance (SMB: the sum of surface accumulation and surface ablation) to changes in surface elevation of the Greenland ice sheet (GrIS) for the MAR (Modèle Atmosphérique Régional: Fettweis, 2007) regional climate model. The motivation is to dynamically adjust SMB as the GrIS evolves, allowing us to force ice sheet models with SMB simulated by MAR while incorporating the SMB–elevation feedback, without the substantial technical challenges of coupling ice sheet and climate models. This also allows us to assess the effect of elevation feedback uncertainty on the GrIS contribution to sea level, using multiple global climate and ice sheet models, without the need for additional, expensive MAR simulations. We estimate this relationship separately below and above the equilibrium line altitude (ELA, separating negative and positive SMB) and for regions north and south of 77° N, from a set of MAR simulations in which we alter the ice sheet surface elevation. These give four "SMB lapse rates", gradients that relate SMB changes to elevation changes. We assess uncertainties within a Bayesian framework, estimating probability distributions for each gradient from which we present best estimates and credibility intervals (CI) that bound 95% of the probability. Below the ELA our gradient estimates are mostly positive, because SMB usually increases with elevation: 0.56 (95% CI: −0.22 to 1.33) kg m−3 a−1 for the north, and 1.91 (1.03 to 2.61) kg m−3 a−1 for the south. Above the ELA, the gradients are much smaller in magnitude: 0.09 (−0.03 to 0.23) kg m−3 a−1 in the north, and 0.07 (−0.07 to 0.59) kg m−3 a−1 in the south, because SMB can either increase or decrease in response to increased elevation. Our statistically founded approach allows us to make probabilistic assessments for the effect of elevation feedback uncertainty on sea level projections (Edwards et al., 2014).

Thanks to its optimal location on the northern Brazilian margin, core MD09-3257 records both ocean circulation and atmospheric changes. The latter occur locally in the form of increased rainfall on the adjacent continent during the cold intervals recorded in Greenland ice and northern North Atlantic sediment cores (i.e., Greenland stadials). These rainfall events are recorded in MD09-3257 as peaks in ln(Ti ∕ Ca). New sedimentary Pa ∕ Th data indicate that mid-depth western equatorial water mass transport decreased during all of the Greenland stadials of the last 40 kyr. Using cross-wavelet transforms and spectrogram analysis, we assess the relative phase between the MD09-3257 sedimentary Pa ∕ Th and ln(Ti ∕ Ca) signals. We show that decreased water mass transport between a depth of ∼1300 and 2300 m in the western equatorial Atlantic preceded increased rainfall over the adjacent continent by 120 to 400 yr at Dansgaard–Oeschger (D–O) frequencies, and by 280 to 980 yr at Heinrich-like frequencies. We suggest that the large lead of ocean circulation changes with respect to changes in tropical South American precipitation at Heinrich-like frequencies is related to the effect of a positive feedback involving iceberg discharges in the North Atlantic. In contrast, the absence of widespread ice rafted detrital layers in North Atlantic cores during D–O stadials supports the hypothesis that a feedback such as this was not triggered in the case of D–O stadials, with circulation slowdowns and subsequent changes remaining more limited during D–O stadials than Heinrich stadials.

Enhanced release of alkalinity from the seafloor, principally driven by anaerobic degradation of organic matter under low-oxygen conditions and associated secondary redox reactions, can increase the carbon dioxide (CO2) buffering capacity of seawater and therefore oceanic CO2 uptake. The Baltic Sea has undergone severe changes in oxygenation state and total alkalinity (TA) over the past decades. The link between these concurrent changes has not yet been investigated in detail. A recent system-wide TA budget constructed for the past 50 years using BALTSEM, a coupled physical–biogeochemical model for the whole Baltic Sea area revealed an unknown TA source. Here we use BALTSEM in combination with observational data and one-dimensional reactive-transport modeling of sedimentary processes in the Fårö Deep, a deep Baltic Sea basin, to test whether sulfate (SO42-) reduction coupled to iron (Fe) sulfide burial can explain the missing TA source in the Baltic Proper. We calculated that this burial can account for up to 26 % of the missing source in this basin, with the remaining TA possibly originating from unknown river inputs or submarine groundwater discharge. We also show that temporal variability in the input of Fe to the sediments since the 1970s drives changes in sulfur (S) burial in the Fårö Deep, suggesting that Fe availability is the ultimate limiting factor for TA generation under anoxic conditions. The implementation of projected climate change and two nutrient load scenarios for the 21st century in BALTSEM shows that reducing nutrient loads will improve deep water oxygen conditions, but at the expense of lower surface water TA concentrations, CO2 buffering capacities and faster acidification. When these changes additionally lead to a decrease in Fe inputs to the sediment of the deep basins, anaerobic TA generation will be reduced even further, thus exacerbating acidification. This work highlights that Fe dynamics plays a key role in the release of TA from sediments where Fe sulfide formation is limited by Fe availability, as exemplified by the Baltic Sea. Moreover, it demonstrates that burial of Fe sulfides should be included in TA budgets of low-oxygen basins.

The mid-Pliocene is a valuable time interval for investigating equilibrium climate at current atmospheric CO2 concentrations because atmospheric CO2 concentrations are thought to have been comparable to the current day and yet the climate and distribution of ecosystems were quite different. One intriguing, but not fully understood, feature of the early to mid-Pliocene climate is the amplified Arctic temperature response and its impact on Arctic ecosystems. Only the most recent models appear to correctly estimate the degree of warming in the Pliocene Arctic and validation of the currently proposed feedbacks is limited by scarce terrestrial records of climate and environment. Here we reconstruct the summer temperature and fire regime from a subfossil fen-peat deposit on west–central Ellesmere Island, Canada, that has been chronologically constrained using cosmogenic nuclide burial dating to 3.9+1.5/-0.5 Ma. The estimate for average mean summer temperature is 15.4±0.8 ∘C using specific bacterial membrane lipids, i.e., branched glycerol dialkyl glycerol tetraethers. This is above the proposed threshold that predicts a substantial increase in wildfire in the modern high latitudes. Macro-charcoal was present in all samples from this Pliocene section with notably higher charcoal concentration in the upper part of the sequence. This change in charcoal was synchronous with a change in vegetation that included an increase in abundance of fire-promoting Pinus and Picea. Paleo-vegetation reconstructions are consistent with warm summer temperatures, relatively low summer precipitation and an incidence of fire comparable to fire-adapted boreal forests of North America and central Siberia. To our knowledge, this site provides the northernmost evidence of fire during the Pliocene. It suggests that ecosystem productivity was greater than in the present day, providing fuel for wildfires, and that the climate was conducive to the ignition of fire during this period. The results reveal that interactions between paleo-vegetation and paleoclimate were mediated by fire in the High Arctic during the Pliocene, even though CO2 concentrations were similar to modern values.

Understanding the role of atmospheric CO2 during past climate changes requires clear knowledge of how it varies in time relative to temperature. Antarctic ice cores preserve highly resolved records of atmospheric CO2 and Antarctic temperature for the past 800,000 years. Here we propose a revised relative age scale for the concentration of atmospheric CO2 and Antarctic temperature for the last deglacial warming, using data from five Antarctic ice cores. We infer the phasing between CO2 concentration and Antarctic temperature at four times when their trends change abruptly. We find no significant asynchrony between them, indicating that Antarctic temperature did not begin to rise hundreds of years before the concentration of atmospheric CO2, as has been suggested by earlier studies.

A significant decrease of dissolved iron (DFe) concentration has been observed after dust addition into mesocosms during the DUst experiment in a low Nutrient low chlorophyll Ecosystem (DUNE), carried out in the summer of 2008. Due to low biological productivity at the experiment site, biological consumption of iron can not explain the magnitude of DFe decrease. To understand processes regulating the observed DFe variation, we simulated the experiment using a one-dimensional model of the Fe biogeochemical cycle, coupled with a simple ecosystem model. Different size classes of particles and particle aggregation are taken into account to describe the particle dynamics. DFe concentration is regulated in the model by dissolution from dust particles and adsorption onto particle surfaces, biological uptake, and photochemical mobilisation of particulate iron. The model reproduces the observed DFe decrease after dust addition well. This is essentially explained by particle adsorption and particle aggregation that produces a high export within the first 24 h. The estimated particle adsorption rates range between the measured adsorption rates of soluble iron and those of colloidal iron, indicating both processes controlling the DFe removal during the experiment. A dissolution timescale of 3 days is used in the model, instead of an instantaneous dissolution, underlining the importance of dissolution kinetics on the short-term impact of dust deposition on seawater DFe. Sensitivity studies reveal that initial DFe concentration before dust addition was crucial for the net impact of dust addition on DFe during the DUNE experiment. Based on the balance between abiotic sinks and sources of DFe, a critical DFe concentration has been defined, above which dust deposition acts as a net sink of DFe, rather than a source. Taking into account the role of excess iron binding ligands and biotic processes, the critical DFe concentration might be applied to explain the short-term variability of DFe after natural dust deposition in various different ocean regions.