Tropospheric ozone (O3) concentrations depend on a combination of hemispheric, regional, and local-scale processes. Estimates of how much O3 is produced locally vs. transported from further afield are essential in air quality management and regulatory policies. Here, a tagged-ozone mechanism within the Weather Research and Forecasting model coupled with chemistry (WRF-Chem) is used to quantify the contributions to surface O3 in the UK from anthropogenic nitrogen oxide (NOx) emissions from inside and outside the UK during May–August 2015. The contribution of the different source regions to three regulatory O3 metrics is also examined. It is shown that model simulations predict the concentration and spatial distribution of surface O3 with a domain-wide mean bias of −3.7 ppbv. Anthropogenic NOx emissions from the UK and Europe account for 13 % and 16 %, respectively, of the monthly mean surface O3 in the UK, as the majority (71 %) of O3 originates from the hemispheric background. Hemispheric O3 contributes the most to concentrations in the north and the west of the UK with peaks in May, whereas European and UK contributions are most significant in the east, south-east, and London, i.e. the UK's most populated areas, intensifying towards June and July. Moreover, O3 from European sources is generally transported to the UK rather than produced in situ. It is demonstrated that more stringent emission controls over continental Europe, particularly in western Europe, would be necessary to improve the health-related metric MDA8 O3 above 50 and 60 ppbv. Emission controls over larger areas, such as the Northern Hemisphere, are instead required to lessen the impacts on ecosystems as quantified by the AOT40 metric.
Greenland ice cores provide information about past climate. Few impurity records covering the past 2 decades exist from Greenland. Here we present results from six firn cores obtained during a 426 km long northern Greenland traverse made in 2015 between the NEEM and the EGRIP deep-drilling stations situated on the western side and eastern side of the Greenland ice sheet, respectively. The cores (9 to 14 m long) are analyzed for chemical impurities and cover time spans of 18 to 53 years (±3 years) depending on local snow accumulation that decreases from west to east. The high temporal resolution allows for annual layers and seasons to be resolved. Insoluble dust, ammonium, and calcium concentrations in the six firn cores overlap, and the seasonal cycles are also similar in timing and magnitude across sites, while peroxide (H2O2) and conductivity both have spatial variations, H2O2 driven by the accumulation pattern, and conductivity likely influenced by sea salt. Overall, we determine a rather constant dust flux over the period, but in the data from recent years (1998–2015) we identify an increase in large dust particles that we ascribe to an activation of local Greenland sources. We observe an expected increase in acidity and conductivity in the mid-1970s as a result of anthropogenic emissions, followed by a decrease due to mitigation. Several volcanic horizons identified in the conductivity and acidity records can be associated with eruptions in Iceland and in the Barents Sea region. From a composite ammonium record we obtain a robust forest fire proxy associated primarily with Canadian forest fires (R=0.49).
Tides significantly affect polar coastlines by modulating ice shelf melt and modifying shelf water properties through transport and mixing. However, the effect of tides on the marine carbonate chemistry in such regions, especially around Antarctica, remains largely unexplored. We address this topic with two case studies in a coastal polynya in the south-eastern Weddell Sea, neighbouring the Ekström Ice Shelf. The case studies were conducted in January 2015 (PS89) and January 2019 (PS117), capturing semi-diurnal oscillations in the water column. These are pronounced in both physical and biogeochemical variables for PS89. During rising tide, advection of sea ice meltwater from the north-east created a fresher, warmer, and more deeply mixed water column with lower dissolved inorganic carbon (DIC) and total alkalinity (TA) content. During ebbing tide, water from underneath the ice shelf decreased the polynya's temperature, increased the DIC and TA content, and created a more stratified water column. The variability during the PS117 case study was much smaller, as it had less sea ice meltwater input during rising tide and was better mixed with sub-ice shelf water. The contrasts in the variability between the two case studies could be wind and sea ice driven, and they underline the complexity and highly dynamic nature of the system. The variability in the polynya induced by the tides results in an air–sea CO2 flux that can range between a strong sink (−24 mmol m−2 d−1) and a small source (3 mmol m−2 d−1) on a semi-diurnal timescale. If the variability induced by tides is not taken into account, there is a potential risk of overestimating the polynya's CO2 uptake by 67 % or underestimating it by 73 %, compared to the average flux determined over several days. Depending on the timing of limited sampling, the polynya may appear to be a source or a sink of CO2. Given the disproportionate influence of polynyas on heat and carbon exchange in polar oceans, we recommend future studies around the Antarctic and Arctic coastlines to consider the timing of tidal currents in their sampling strategies and analyses. This will help constrain variability in oceanographic measurements and avoid potential biases in our understanding of these highly complex systems.
The role of icebergs in narrow fjords hosting marine terminating glaciers in Greenland is poorly understood, even though icebergs provide a substantial freshwater flux that can exceed the subglacial discharge. Iceberg melt is distributed at depth, contributing to fjord stratification, thus impacting melt and dynamics of the glacier front. We model the high-silled Ilulissat Icefjord in Western Greenland with the MITgcm ocean model, using the IceBerg package to study the effect of icebergs on fjord properties, and compare our results with available observations from 2014. We find the subglacial discharge plume to be the primary driver of the seasonality of circulation, glacier melt and iceberg melt. Icebergs are necessary to include to correctly understand the properties of Ilulissat Icefjord, since they modify the fjord in three main ways: First, icebergs cool and freshen the water column within their vertical extent; Second, icebergs depress the neutral buoyancy depth of the plume and the outflow route of glacially modified water; Third, icebergs modify the deep basin, below their vertical extent, due to both increased entrainment of glacially modified water into the fjord, and iceberg modification of the incoming ambient water. Furthermore, the depressed neutral buoyancy depth of the plume limits melt to the deep section of the front of Sermeq Kujalleq (Jakobshavn Isbræ) even during peak summer, and thus promotes undercutting. We postulate that the impact of icebergs on the neutral buoyancy depth of the plume is a key mechanism connecting iceberg melange and glacier calving, independent of mechanical support.
Project: EC | COMMON SENSE (614155), EC | MYOCEAN2 (283367)
Since 2000, and for the following 20 years, hydrological data of the Mediterranean Sea, with a particular focus on the western and central Mediterranean sub-basins, have been acquired to study the hydrodynamics at both coastal and open sea scales. In total, 1468 hydrological casts were realized in 29 oceanographic cruises planned due to scientific purposes linked with funding research projects but were also sometimes driven by sea conditions and type of vessel. After accurate quality assurance and control, following standard procedures, all hydrological data were included in four online public open-access repositories in SEANOE (SEA scieNtific Open data Edition), available from https://doi.org/10.17882/87567 (Ribotti et al., 2022). Hydrological and dissolved oxygen data are always present in all of the datasets, whereas pH, fluorescence, turbidity, and chromophoric dissolved organic matter (CDOM) are available just for some cruises. Samplings were carried out mainly along transects, with some repetition over the years. The results of two data analyses, i.e., staircase systems in the Tyrrhenian Sea and in the Algero-Provençal sub-basin and spreading of the Western Mediterranean Transient, are mentioned.
We present a record of melt events obtained from the East Greenland Ice Core Project (EastGRIP) ice core in central northeastern Greenland, covering the largest part of the Holocene. The data were acquired visually using an optical dark-field line scanner. We detect and describe melt layers and lenses, seen as bubble-free layers and lenses, throughout the ice above the bubble–clathrate transition. This transition is located at 1150 m depth in the EastGRIP ice core, corresponding to an age of 9720 years b2k. We define the brittle zone in the EastGRIP ice core as that from 650 to 950 m depth, where we count on average more than three core breaks per meter. We analyze melt layer thicknesses, correct for ice thinning, and account for missing layers due to core breaks. Our record of melt events shows a large, distinct peak around 1014 years b2k (986 CE) and a broad peak around 7000 years b2k, corresponding to the Holocene Climatic Optimum. In total, we can identify approximately 831 mm of melt (corrected for thinning) over the past 10 000 years. We find that the melt event from 986 CE is most likely a large rain event similar to that from 2012 CE, and that these two events are unprecedented throughout the Holocene. We also compare the most recent 2500 years to a tree ring composite and find an overlap between melt events and tree ring anomalies indicating warm summers. Considering the ice dynamics of the EastGRIP site resulting from the flow of the Northeast Greenland Ice Stream (NEGIS), we find that summer temperatures must have been at least 3 ± 0.6 ∘C warmer during the Early Holocene compared to today.
The documents in these folders represent part of the qualitative data collection documentation. Research has been performed in Flanders (Belgium) in 2016 and 2017. Involved stakehodlers were flemish sugar beet farmers, processors as well as other value chain members. Though, the main stakeholders involved were farmers. The raw data cannot be published. Anonymized interview transcripts and focus group transcripts exist. However, as indicated in the informed consent, farmers did not agree to the raw data being published. The codes that resulted from data analysis are in this folder. Interview questions differed slightly from farmer to farmer as follow up questions may have been posed if needed. First interviews were performed, then focus groups were conducted and finally a workshop was organized. The qualitative reserach followed the research strategy and plan determined by the SUFISA project. On the project webpage (https://www.sufisa.eu/) more information can be found.
Ehlert von Ahn, Cátia Milene; Böttcher, Michael Ernst; Dellwig, Olaf; Schmiedinger, Iris; Scholten, Jan Christoph;
Ehlert von Ahn, Cátia Milene; Böttcher, Michael Ernst; Dellwig, Olaf; Schmiedinger, Iris; Scholten, Jan Christoph;
Publisher: PANGAEA - Data Publisher for Earth & Environmental Science
Project: EC | SGDBALTIC (293499)
Short sediment cores were taken at six stations in Wismar Bay, southern Baltic Sea (Germany) in May 2019 using a Rumohr-Lot device. Our aim in this study was to investigate the role of diagenetic element fluxes and different fresh water sources, including submarine groundwater discharge, on the water column in the bay. Porewaters were extracted from the sediment cores by applying the rhizon technique at a resolution between 2 and 5 cm. The porewaters were analyzed for major and trace metals and selected nutrients using a ICP-OES (iCAP, 7400, Duo Thermo Fischer Scientific), total sulphide by a Specord 40 spectrophotometer (Analytik Jena), dissolved inorganic carbon (DIC) and δ13CDIC using an isotope gas mass spectrometre (MAT 253) coupled to a Gasbench II, and δ18OH2O, and δ2HH2O using a CRDS system (laser cavity-ring-down-spectroscopy, Picarro L2140- I). Sediment cores were further sliced at 2 to 4 cm resolution and each freeze-dried solid subsample was analyzed for contents of total carbon, nitrogen, and sulphur using an Elemental Analyzer (Euro Vector EuroEA 3, 052), inorganic carbon using an Elemental Analyzer multi EA (Analytik Jena), total mercury by a DMA-80 analyzer, and HCl-extractable Pb, Mn and Fe using an ICP-OES (iCAP, 7400, Duo Thermo Fischer Scientific).