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Abstract The discovery of stimuli-responsive high affinity host–guest pairs with potential applications under biologically relevant conditions is a challenging goal. This work reports a high-affini...

This data set displays a refined age scale for the U1361A marine sediment core (64.41°S, 143.89°E, 3,454 m water depth), recovered from the continental rise offshore of the Wilkes Subglacial Basin, during the Integrated Ocean Drilling Program (IODP) Expedition (Escutia et al. 2011). This age scale is a refined version of the age scale published in Wilson et al. 2018. Here we use the AICC2012 ice core chronology as a reference curve in order to compare the late Pleistocene sediment core data from U1361A to the TALDICE ice core record. Specifically, we refine the existing U1361A age model through the alignment of barium/aluminium (Ba/Al) ratios from XRF-scanning7 with the EDC δD record on the AICC2012 age scale. We apply a conservative tuning strategy to align the two records, using tie points (derived by visual matching) only at the mid-points of the major glacial terminations I-V. Over the interval of interest for the present study (i.e. ~100-350 ka), the new age model for core U1361 differs by only 0 to 6 ka compared to the previous age model in which the sedimentation rate was assumed to be constant. The Nd and IBRD (ice rafted debris) and 143 Nd/144 Nd records for the U1361A published in Wilson et al. (2018) are drawn on the refined age scale. IBRD was measured by weighing after wet-sievingIBRD (ire rafted debris) and 143Nd/144Nd records of the U1361A sediment core (Wilson et al. 2018) drawn of the refined age scale tuned on the AICC2012 chronology for EDC (Bazin et al. 2013)

This data set displays a refined age scale for the U1361A marine sediment core (64.41°S, 143.89°E, 3,454 m water depth), recovered from the continental rise offshore of the Wilkes Subglacial Basin, during the Integrated Ocean Drilling Program (IODP) Expedition (Escutia et al. 2011). This age scale is a refined version of the age scale published in Wilson et al. 2018. Here we use the AICC2012 ice core chronology as a reference curve in order to compare the late Pleistocene sediment core data from U1361A to the TALDICE ice core record. Specifically, we refine the existing U1361A age model through the alignment of barium/aluminium (Ba/Al) ratios from XRF-scanning7 with the EDC δD record on the AICC2012 age scale. We apply a conservative tuning strategy to align the two records, using tie points (derived by visual matching) only at the mid-points of the major glacial terminations I-V. Over the interval of interest for the present study (i.e. ~100-350 ka), the new age model for core U1361 differs by only 0 to 6 ka compared to the previous age model in which the sedimentation rate was assumed to be constant. The Nd and IBRD (ice rafted debris) and 143 Nd/144 Nd records for the U1361A published in Wilson et al. (2018) are drawn on the refined age scale. 2 s.e. = internal precision (2s level) on sample measurement 2 s.d. = external reproducibility estimated from the within-session standard deviation (2s.d.) on JNdi-1 standards Over the course of the analyses, measurements of rock standard BCR-2 gave 143Nd/144Nd = 0.512640 ± 0.000016 (n=31)IBRD (ire rafted debris) and 143Nd/144Nd records of the U1361A sediment core (Wilson et al. 2018) drawn of the refined age scale tuned on the AICC2012 chronology for EDC (Bazin et al. 2013)

Concentrations of dissolved micronutrient trace metals (Fe, Zn, Ni, Cu, Cd, Pb, Mn) in seawater, sea ice, and melt ponds collected on the US GEOTRACES Arctic cruise (HLY1502, GN01) from August to October 2015.

As part of the Model Intercomparison Project on the climatic response to Volcanic forcing (VolMIP), several climate modeling centers performed a coordinated pre-study experiment with interactive stratospheric aerosol models simulating the volcanic aerosol cloud from an eruption resembling the 1815 Mt. Tambora eruption (VolMIP-Tambora ISA ensemble). The pre-study provided the ancillary ability to assess intermodel diversity in the radiative forcing for a large stratospheric-injecting equatorial eruption when the volcanic aerosol cloud is simulated interactively. An initial analysis of the VolMIP-Tambora ISA ensemble showed large disparities between models in the stratospheric global mean aerosol optical depth (AOD). In this study, we now show that stratospheric global mean AOD differences among the participating models are primarily due to differences in aerosol size, which we track here by effective radius. We identify specific physical and chemical processes that are missing in some models and/or parameterized differently between models, which are together causing the differences in effective radius. In particular, our analysis indicates that interactively tracking hydroxyl radical (OH) chemistry following a large volcanic injection of sulfur dioxide (SO2) is an important factor in allowing for the timescale for sulfate formation to be properly simulated. In addition, depending on the timescale of sulfate formation, there can be a large difference in effective radius and subsequently AOD that results from whether the SO2 is injected in a single model grid cell near the location of the volcanic eruption, or whether it is injected as a longitudinally averaged band around the Earth.

In this dataset, we present Fe, Na and Ca concentration and fluxes retrieved from the North Greenland Eemian Ice Drilling (NEEM) ice core project, covering the last 108 kyrs. The sampling resolution was 110 cm. To ensure an effective dissolution of Fe particles, samples were acidified to pH 1 using Suprapure nitric acid and stored at room temperature for 1 month before the analysis. The ice samples were analyzed with an Inductively Coupled Plasma Single Quadrupole Mass Spectrometer equipped with a quartz Scott spray chamber. Limits of Detection, calculated as three times the standard deviation of the blanks, were 0.8 µg L-1 for 57Fe, 1 µg L-1 for Ca and 3 µg L-1 for Na. Our results show that Holocene Fe fluxes (0.042 -11.7 kyr b2k, 0.5 mg m-2 yr-1) at the NEEM site were four times lower than the average recorded over the last glacial period (11.7– 108 kyr b2k, 2.0 mg m-2 yr-1), while they were greater during the Last Glacial Maximum (LGM, 14.5 – 26.5 kyr b2k, 3.6 mg m-2 yr-1) and Marine Isotope Stage 4 (MIS 4, 60 - 71 kyr b2k, 5.8 mg m-2 yr-1). We present Fe, Ca and Na concentration and fluxes. Dating (GICC05modelext-NEEM-1) and accumulation data are from Rasmussen et al., 2013.

We present the full dD of water and d18O of water data at 55 cm resolution on the EPICA Dome C ice core from the near surface (6.6 m) to the bottom (3190 m), hence covering the last 800 ka. The EPICA Dome C ice core has been drilled in Antarctica (-75.1°S; 123.395°E; 3233 m elevation) between 1996 and 2004 and measurements performed from 2001 to 2020. Some of the data were already published in previous published studies (Jouzel et al. 2007; Stenni et al. 2001, 2004, 2010) but corrections were performed in the present data file. dD measurements from Jouzel et al. (2007) were obtained using a uranium reduction method. In this new dataset, these results over the last 800 ka are combined with new dD measurements (760 samples) performed over the deepest 418 m using a Picarro L2130-i (cavity ring-down spectroscopy). The d18O measurements presented here were performed using a water-CO2 equilibration method. This dataset goes along with a paper published in Nature Geoscience (Landais et al., 2021).

The phycotoxin contents were measured in 2013 during a long-term mesocosm CO2 experiment in Gullmar Fjord (Sweden). The natural plankton community was enclosed in ten pelagic mesocosms and five of the mesocosms were enriched with CO2 to simulate end-of the century ocean acidification while the others served as controls. The data set was used to assess the impact of ocean acidification on harmful algal bloom species and toxins. The Fjord-sample data were taken in close proximity of the mesocosms and were used to assess the phycotoxin contents in the surrounding waters.

Photosynthesis and respiration cause distinct chemical microenvironments within cyanobacterial aggregates. Here, we used microsensors and a diffusion–reaction model to characterize gradients in carbonate chemistry and investigate how these are affected by ocean acidification in Baltic vs. Pacific aggregates (Nodularia and Dolichospermum vs. Trichodesmium). Microsensor measurements of O2 and pH were performed under in situ and expected future pCO2 levels on Nodularia and Dolichospermum aggregates collected in the Baltic Sea. Under in situ conditions, O2 and pH levels within the aggregates covered ranges of 80–175% air saturation and 7.7–9.4 in dark and light, respectively. Carbon uptake in the light was predicted to reduce HCO3− by 100–150 μmol/L and CO2 by 3–6 μmol/L in the aggregate center compared to outside, inducing strong CO2 depletion (down to 0.5 μmol/L CO2 remaining in the center) even when assuming that HCO3− covered 80–90% of carbon uptake. Under ocean acidification conditions, enhanced CO2 availability allowed for significantly lower activity of carbon concentrating mechanisms, including a reduction of the contribution of HCO3− to carbon uptake by up to a factor of 10. The magnification of proton gradients under elevated pCO2 that was predicted based on a lower buffer capacity was observed in measurements despite a concurrent decrease in photosynthetic activity. In summary, we provide a quantitative image of the inorganic carbon environment in cyanobacterial aggregates under present-day and expected future conditions, considering both the individual and combined effects of the chemical and biological processes that shape these environments. In order to allow full comparability with other ocean acidification data sets, the R package seacarb (Gattuso et al, 2021) was used to compute a complete and consistent set of carbonate system variables, as described by Nisumaa et al. (2010). In this dataset the original values were archived in addition with the recalculated parameters (see related PI). The date of carbonate chemistry calculation by seacarb is 2022-04-28.

Startle response behaviours are important in predator avoidance and escape for a wide array of animals. For many marine invertebrates, however, startle response behaviours are understudied, and the effects of global change stressors on these responses are unknown. We exposed two size classes of blue mussels (Mytilus edulis * trossulus) to different combinations of temperature (15 and 19 °C) and pH (8.2 and 7.5 pHT) for 3 months and subsequently measured individual time to open following a tactile predator cue (i.e. startle response time) over a series of four consecutive trials. Time to open was highly repeatable in the short term and decreased linearly across the four trials. Individuals from the larger size class had a shorter time to open than their smaller-sized counterparts. High temperature increased time to open compared to low temperature, while pH had no effect. These results suggest that bivalve time to open is repeatable, related to relative vulnerability to predation and affected by temperature. Given that increased closure times impact feeding and respiration, the effect of temperature on closure duration may play a role in the sensitivity to ocean warming in this species and contribute to ecosystem level effects. In order to allow full comparability with other ocean acidification data sets, the R package seacarb (Gattuso et al, 2021) was used to compute a complete and consistent set of carbonate system variables, as described by Nisumaa et al. (2010). In this dataset the original values were archived in addition with the recalculated parameters (see related PI). The date of carbonate chemistry calculation by seacarb is 2021-03-30.