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Oceanic very short-lived substances (VSLSs), such as bromoform (CHBr3), contribute to stratospheric halogen loading and, thus, to ozone depletion. However, the amount, timing, and region of bromine delivery to the stratosphere through one of the main entrance gates, the Indian summer monsoon circulation, are still uncertain. In this study, we created two bromoform emission inventories with monthly resolution for the tropical Indian Ocean and west Pacific based on new in situ bromoform measurements and novel ocean biogeochemistry modeling. The mass transport and atmospheric mixing ratios of bromoform were modeled for the year 2014 with the particle dispersion model FLEXPART driven by ERA-Interim reanalysis. We compare results between two emission scenarios: (1) monthly averaged and (2) annually averaged emissions. Both simulations reproduce the atmospheric distribution of bromoform from ship- and aircraft-based observations in the boundary layer and upper troposphere above the Indian Ocean reasonably well. Using monthly resolved emissions, the main oceanic source regions for the stratosphere include the Arabian Sea and Bay of Bengal in boreal summer and the tropical west Pacific Ocean in boreal winter. The main stratospheric injection in boreal summer occurs over the southern tip of India associated with the high local oceanic sources and strong convection of the summer monsoon. In boreal winter more bromoform is entrained over the west Pacific than over the Indian Ocean. The annually averaged stratospheric injection of bromoform is in the same range whether using monthly averaged or annually averaged emissions in our Lagrangian calculations. However, monthly averaged emissions result in the highest mixing ratios within the Asian monsoon anticyclone in boreal summer and above the central Indian Ocean in boreal winter, while annually averaged emissions display a maximum above the west Indian Ocean in boreal spring. In the Asian summer monsoon anticyclone bromoform atmospheric mixing ratios vary by up to 50 % between using monthly averaged and annually averaged oceanic emissions. Our results underline that the seasonal and regional stratospheric bromine injection from the tropical Indian Ocean and west Pacific critically depend on the seasonality and spatial distribution of the VSLS emissions.

Five hormone-treated female Japanese silver eels Anguilla japonica were tagged with ultrasonic transmitters and released by submersible in the West Pacific at seamounts of the West Mariana Ridge, their supposed spawning grounds. Four eels were tracked for 60 to 423 min in the vicinity of the seamounts. They did not settle at the seamounts but swam at a mean speed of 0.37 m s 1 into open water above deep ground. Their mean swimming depth ranged from 81 to 172 m. Experiments suggest that pre-matured A. japonica migrate to their spawning grounds in temperate warm water and at shallow depths.

The NMR-based configurational analysis of complex marine natural products is still not a routine task. Different NMR parameters are used for the assignment of the relative configuration: NOE/ROE, homo- and heteronuclear J couplings as well as anisotropic parameters. The combined distance geometry (DG) and distance bounds driven dynamics (DDD) method allows a model-free approach for the determination of the relative configuration that is invariant to the choice of an initial starting structure and does not rely on comparisons with (DFT) calculated structures. Here, we will discuss the configurational analysis of five complex marine natural products or synthetic derivatives thereof: the cis-palau’amine derivatives 1a and 1b, tetrabromostyloguanidine (1c), plakilactone H (2), and manzamine A (3). The certainty of configurational assignments is evaluated in view of the accuracy of the NOE/ROE data available. These case studies will show the prospective breadth of application of the DG/DDD method.

Organisms’ size and shape have a profound influence on ecophysiological performance and evolutionary fitness, suggesting a link between morphology and diversity. While unimodal relationships between size and species richness were found for many taxa(1–4), much less is known on how richness is related to shape, in particular in the microbial realm. Here we analyse a novel globally extensive data set of marine unicellular phytoplankton, the major group of photosynthetic microbes, which exhibit an astounding diversity of cell sizes and shapes(5). We quantify the variation in size and shape and explore their effects on taxonomic diversity(6, 7). We find that cells of intermediate volume exhibit the greatest shape variation, with shapes ranging from oblate to extremely elongated forms, while very small and large cells are mostly compact (e.g., spherical or cubic). We show that cell shape has a strong effect on phytoplankton diversity, comparable in magnitude to the effect of cell volume, with both traits explaining up to 92% of the variance in phytoplankton diversity. Species richness decays exponentially with cell elongation and displays a log-normal dependence on cell volume, peaking for compact cells of intermediate volume. Our findings highlight different selective pressures and constraints on phytoplankton of different geometry and improve our understanding of the evolutionary rules of life.

Die Finanzierung globaler Umweltpolitik stellt sowohl aufgrund der Grosenordnung der erforderlichen Mittel als auch angesichts der damit verbundenen weltweiten Verteilungskonflikte zwischen Nettozahlern und Nettoempfangern zu den schwierigsten, aber notwendigsten Aufgaben einer Reform des internationalen Institutionengefuges. Die Brisanz dieser Thematik wird angesichts des in den OECD-Landern stetig sinkenden BSP-Anteils fur Leistungen zur Entwicklungszusammenarbeit bei zunehmendem Finanzbedarf und fortwahrender Kritik dieser Lander an ineffizienten und wenig effektiven Strukturen internationaler Organisationen beim Einsatz finanzieller Mittel deutlich.

The Ordos Block in the western part of the North China Craton is enigmatic in having contrasting topographic structure in the northern and southern parts, while previous geophysical studies show little difference in crustal and upper mantle structure across the region. Here we present a new model of upper mantle structure in the Ordos Block region in order to test the importance of mantle heterogeneity for topographic differences. Our model is based on P- and S-wave seismic receiver functions calculated for data from 171 stations. It documents the presence of an uppermost mantle low-velocity zone between the Mid Lithospheric Discontinuity (MLD) and the Lehmann discontinuity. Clear converters at the 410 and 660 km discontinuities show constant Mantle Transition Zone (MTZ) thickness within the Ordos Block region, which indicates that no deep mantle thermal anomaly affects its present dynamics. However, the amplitude of the MTZ-converters is higher in the southern than the northern Ordos Block. In contrast, the conversions from MLD and the Lehmann discontinuity are strongest in Northern Ordos, which we interpret as a block with essentially preserved cratonic lithospheric mantle. We speculate that smaller amplitudes of the MLD and Lehmann converters in Southern than Northern Ordos may be related to either rheological weakening of cratonic lithosphere during the Mesozoic convergence between the North and South (Yangtze) China Cratons, or northeast extrusion of Tibetan lower crust and upper mantle in the Cenozoic caused by the India-Asia collision.

Groundwater seepage leads to the formation of theater-headed valleys (THVs) in unconsolidated sediments. In bedrock, the role of groundwater in THV development remains disputed. Here, we integrate field and remote-sensing observations from Gnejna Valley (Maltese Islands) with numerical modeling to demonstrate that groundwater seepage can be the main driver of THV formation in jointed limestone overlying clays. The inferred erosion mechanisms entail (1) widening of joints and fractures by fluid pressure and dissolution and (2) creeping of an underlying clay layer, which lead to slope failure at the valley head and its upslope retreat. The latter is slower than the removal of the talus by creep and sliding on the valley bed. The location and width of THVs are controlled by the location of the master fault and the extent of the damage zone, respectively. The variability of seepage across the fault zone determines the shape of the valley head, with an exponential decrease in seepage away from the fault giving rise to a theater-shaped head that best matches that of Gnejna Valley. Our model may explain the formation of THVs by groundwater in jointed, strong-over-weak chemical sedimentary lithologies, particularly in arid terrestrial settings. peer-reviewed