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Oceanic very short-lived substances (VSLSs), such as bromoform (CHBr3), contribute to stratospheric halogen loading and, thus, to ozone depletion. However, the amount, timing, and region of bromine delivery to the stratosphere through one of the main entrance gates, the Indian summer monsoon circulation, are still uncertain. In this study, we created two bromoform emission inventories with monthly resolution for the tropical Indian Ocean and west Pacific based on new in situ bromoform measurements and novel ocean biogeochemistry modeling. The mass transport and atmospheric mixing ratios of bromoform were modeled for the year 2014 with the particle dispersion model FLEXPART driven by ERA-Interim reanalysis. We compare results between two emission scenarios: (1) monthly averaged and (2) annually averaged emissions. Both simulations reproduce the atmospheric distribution of bromoform from ship- and aircraft-based observations in the boundary layer and upper troposphere above the Indian Ocean reasonably well. Using monthly resolved emissions, the main oceanic source regions for the stratosphere include the Arabian Sea and Bay of Bengal in boreal summer and the tropical west Pacific Ocean in boreal winter. The main stratospheric injection in boreal summer occurs over the southern tip of India associated with the high local oceanic sources and strong convection of the summer monsoon. In boreal winter more bromoform is entrained over the west Pacific than over the Indian Ocean. The annually averaged stratospheric injection of bromoform is in the same range whether using monthly averaged or annually averaged emissions in our Lagrangian calculations. However, monthly averaged emissions result in the highest mixing ratios within the Asian monsoon anticyclone in boreal summer and above the central Indian Ocean in boreal winter, while annually averaged emissions display a maximum above the west Indian Ocean in boreal spring. In the Asian summer monsoon anticyclone bromoform atmospheric mixing ratios vary by up to 50 % between using monthly averaged and annually averaged oceanic emissions. Our results underline that the seasonal and regional stratospheric bromine injection from the tropical Indian Ocean and west Pacific critically depend on the seasonality and spatial distribution of the VSLS emissions.

Groundwater seepage leads to the formation of theater-headed valleys (THVs) in unconsolidated sediments. In bedrock, the role of groundwater in THV development remains disputed. Here, we integrate field and remote-sensing observations from Gnejna Valley (Maltese Islands) with numerical modeling to demonstrate that groundwater seepage can be the main driver of THV formation in jointed limestone overlying clays. The inferred erosion mechanisms entail (1) widening of joints and fractures by fluid pressure and dissolution and (2) creeping of an underlying clay layer, which lead to slope failure at the valley head and its upslope retreat. The latter is slower than the removal of the talus by creep and sliding on the valley bed. The location and width of THVs are controlled by the location of the master fault and the extent of the damage zone, respectively. The variability of seepage across the fault zone determines the shape of the valley head, with an exponential decrease in seepage away from the fault giving rise to a theater-shaped head that best matches that of Gnejna Valley. Our model may explain the formation of THVs by groundwater in jointed, strong-over-weak chemical sedimentary lithologies, particularly in arid terrestrial settings. peer-reviewed

Oceanic dissolved organic carbon (DOC) is an important carbon pool, similar in magnitude to atmospheric CO2, but the fate of its oldest forms is not well understood1, 2. Hot hydrothermal circulation may facilitate the degradation of otherwise un-reactive dissolved organic matter, playing an important role in the long-term global carbon cycle. The oldest, most recalcitrant forms of DOC, which make up most of oceanic DOC, can be recovered by solid-phase extraction. Here we present measurements of solid-phase extractable DOC from samples collected between 2009 and 2013 at seven vent sites in the Atlantic, Pacific and Southern oceans, along with magnesium concentrations, a conservative tracer of water circulation through hydrothermal systems. We find that magnesium and solid-phase extractable DOC concentrations are correlated, suggesting that solid-phase extractable DOC is almost entirely lost from solution through mineralization or deposition during circulation through hydrothermal vents with fluid temperatures of 212–401 °C. In laboratory experiments, where we heated samples to 380 °C for four days, we found a similar removal efficiency. We conclude that thermal degradation alone can account for the loss of solid-phase extractable DOC in natural hydrothermal systems, and that its maximum lifetime is constrained by the timescale of hydrothermal cycling, at about 40 million years3.

Two variants of sea-surface temperature (SST) dipole indices for the South Atlantic Ocean (SAO) has been previously described representing: (1) the South Atlantic subtropical dipole (SASD) supposedly peaking in austral summer and (2) the SAO dipole (SAOD) in winter. In this study, we present the analysis of observational data sets (1985–2014) showing the SASD and SAOD as largely constituting the same mode of ocean–atmosphere interaction reminiscent of the SAOD structure peaking in winter. Indeed, winter is the only season in which the inverse correlation between the northern and southern poles of both indices is statistically significant. The observed SASD and SAOD indices exhibit robust correlations (P ≤ 0.001) in all seasons and these are reproduced by 54 of the 63 different models of the Coupled Models Intercomparison Project analysed. Their robust correlations notwithstanding the SASD and SAOD indices appear to better capture different aspects of SAO climate variability and teleconnections

To limit global warming to 1.5 °C, vast amounts of CO2 will have to be removed from the atmosphere via Carbon Dioxide Removal (CDR). Enhancing the CO2 sequestration of ecosystems will require not just one approach but a portfolio of CDR options, including so-called nature-based approaches alongside CDR options that are perceived as more technical. Creating a CDR “supply curve” would however imply that all carbon removals are considered to be perfect substitutes. The various co-benefits of nature-based CDR approaches militate against this. We discuss this aspect of nature-based solutions in connection with the enhancement of blue carbon ecosystems (BCE) such as mangrove or seagrass habitats. Enhancing BCEs can indeed contribute to CO2 sequestration, but the value of their carbon storage is low compared to the overall contribution of their ecosystem services to wealth. Furthermore, their property rights are often unclear, i.e. not comprehensively defined or not enforced. Hence, payment schemes that only compensate BCE carbon sequestration could create tradeoffs at the expense of other important, often local, ecosystem services and might not result in socially optimal outcomes. Accordingly, one chance for preserving and restoring BCEs lies in the consideration of all services in potential compensation schemes for local communities. Also, local contexts, management structures, and benefit-sharing rules are crucial factors to be taken into account when setting up international payment schemes to support the use of BCEs and other nature- or ecosystem-based CDR. However, regarding these options as the only hope of achieving more CDR will very probably not bring about the desired outcome, either for climate mitigation or for ecosystem preservation. Unhalted degradation, in turn, will make matters worse due to the large amounts of stored carbon that would be released. Hence, countries committed to climate mitigation in line with the Paris targets should not hide behind vague pledges to enhance natural sinks for removing atmospheric CO2 but commit to scaling up engineered CDR.

The well-established dynamical global vegetation, hydrology, and crop growth model LPJmL is extended with a terrestrial nitrogen cycle to account for nutrient limitations. In particular, processes of soil nitrogen dynamics, plant uptake, nitrogen allocation, response of photosynthesis and maintenance respiration to varying nitrogen concentrations in plant organs, and agricultural nitrogen management are included in the model. All new model features are described in full detail and the results of a global simulation of the historic past (1901–2009) are presented for evaluation of the model performance. We find that the implementation of nitrogen limitation significantly improves the simulation of global patterns of crop productivity. Regional differences in crop productivity, which had to be calibrated via a scaling of the maximum leaf area index, can now largely be reproduced by the model, except for regions where fertilizer inputs and climate conditions are not the yield-limiting factors. Furthermore, it can be shown that land use has a strong influence on nitrogen losses, increasing leaching by 93%.

Volcanic archipelagos are a source of numerous on- and offshore geohazards, including explosive eruptions and potentially tsunamigenic large-scale flank collapses. Fogo Island in the southern Cape Verdes is one of the most active volcanoes in the world, making it both prone to collapse (as evidenced by the c. 73 ka Monte Amarelo volcanic flank collapse), and a source of widely distributed tephra and volcanic material. The offshore distribution of the Monte Amarelo debris avalanche deposits and the surrounding volcaniclastic apron were previously mapped using only medium-resolution bathymetric data. Here, using recently acquired, higher-resolution acoustic data, we revisit Fogo's flank collapse and find evidence suggesting that the deposition of hummocky volcanic debris originating from the failed eastern flank most likely triggered the contemporaneous, multi-phase failure of pre-existing seafloor sediments. Additionally, we identify, for the first time, multiple mass-transport deposits in the southern part of the volcaniclastic apron of Fogo and Santiago based on the presence of acoustically chaotic deposits in parametric echo sounder data and volcaniclastic turbiditic sands in recovered cores. These preliminary findings indicate a long and complex history of instability on the southern slopes of Fogo and suggest that Fogo may have experienced multiple flank collapses.