Catalysis is a core area of science that lies at the heart of the chemicals industry - an immensely successful and important part of the overall UK economy, where in recent years the UK output has totalled over £50B annually and is ranked 7th in the world. This position is being maintained in the face of immense competition worldwide. For the UK to sustain its leading position it is essential that innovation in research is maintained, to achieve which the UK Catalysis Hub was established in 2013; and has succeeded over the last four years in bringing together over 40 university groups for innovative and collaborative research programmes in this key area of contemporary science. The success of the Hub can be attributed to its inclusive and open ethos which has resulted in many groups joining its network since its foundation in 2013; to its strong emphasis on collaboration; and to its physical hub on the Harwell campus in close proximity to the Diamond synchrotron, ISIS neutron source and Central Laser Facility, whose successful exploitation for catalytic science has been a major feature of the recent science of the Hub. The next phase of the Catalysis Hub will build on this success and while retaining the key features and structure of the current hub will extend its programmes both nationally and internationally. The core activities to which the present proposal relates include our coordinating activities, comprising our influential and well attended conference, workshop and training programmes, our growing outreach and dissemination work as well as the core management functions. The core catalysis laboratory facilities within the research complex will also be maintained and developed and two key generic scientific and technical developments will be undertaken concerning first sample environment and high throughput capabilities especially relating to facilities experimentation; and secondly to data management and analysis. The core programme will coordinate the scientific themes of the Hub, which in the initial stages of the next phase will comprise: - Optimising, predicting and designing new catalysts - Water - energy nexus - Catalysis for the Circular Economy and Sustainable Manufacturing - Biocatalysis and biotransformations The Hub structure is intrinsically multidisciplinary including extensive input from engineering as well as science disciplines and with strong interaction and cross-fertilisation between the different themes. The thematic structure will allow the Hub to cover the major areas of current catalytic science

The international offshore energy industry currently faces the triple challenges of an oil price expected to remain less than $50 a barrel, significant expensive decommissioning commitments of old infrastructure (especially North Sea) and small margins on the traded commodity price per KWh of offshore renewable energy. Further, the offshore workforce is ageing as new generations of suitable graduates prefer not to work in hazardous places offshore. Operators therefore seek more cost effective, safe methods and business models for inspection, repair and maintenance of their topside and marine offshore infrastructure. Robotics and artificial intelligence are seen as key enablers in this regard as fewer staff offshore reduces cost, increases safety and workplace appeal. The long-term industry vision is thus for a completely autonomous offshore energy field, operated, inspected and maintained from the shore. The time is now right to further develop, integrate and de-risk these into certifiable evaluation prototypes because there is a pressing need to keep UK offshore oil and renewable energy fields economic, and to develop more productive and agile products and services that UK startups, SMEs and the supply chain can export internationally. This will maintain a key economic sector currently worth £40 billion and 440,000 jobs to the UK economy, and a supply chain adding a further £6 billion in exports of goods and services. The ORCA Hub is an ambitious initiative that brings together internationally leading experts from 5 UK universities with over 30 industry partners (>£17.5M investment). Led by the Edinburgh Centre of Robotics (HWU/UoE), in collaboration with Imperial College, Oxford and Liverpool Universities, this multi-disciplinary consortium brings its unique expertise in: Subsea (HWU), Ground (UoE, Oxf) and Aerial robotics (ICL); as well as human-machine interaction (HWU, UoE), innovative sensors for Non Destructive Evaluation and low-cost sensor networks (ICL, UoE); and asset management and certification (HWU, UoE, LIV). The Hub will provide game-changing, remote solutions using robotics and AI that are readily integratable with existing and future assets and sensors, and that can operate and interact safely in autonomous or semi-autonomous modes in complex and cluttered environments. We will develop robotics solutions enabling accurate mapping of, navigation around and interaction with offshore assets that support the deployment of sensors networks for asset monitoring. Human-machine systems will be able to co-operate with remotely located human operators through an intelligent interface that manages the cognitive load of users in these complex, high-risk situations. Robots and sensors will be integrated into a broad asset integrity information and planning platform that supports self-certification of the assets and robots.

Autonomous Underwater Vehicles (AUVs) can be loaded with chemical sensors and sent on missions to conduct high-resolution surveys in the deep sea. They are of interest to the oil and gas industry, as, if fitted with the right sensors, they can be used to help monitor subsea pipelines for leaks and also pinpoint new hydrocarbon reserves under the seafloor by measuring the chemical composition (e.g. the dissolved methane concentration) of the waters above. However, AUVs are prohibitively expensive for routine monitoring and exploration, and often require a large and expensive ship to be present on the surface. A new innovation in AUV technology is the microsub. These miniature AUVs can cost about 2% of the price of a traditional large AUV and are small enough to be launched from a small inflatable boat or the shoreline. They can reach complex areas (shallow waters and reefs) that larger AUVs cannot get to, and can operate in large swarms to efficiently survey a large area. The main drawback of microsubs is that they have limited onboard space and power, meaning that many sensor systems cannot be carried. This means the measurements performed by microsubs are very basic. No methane sensors are currently available that can be deployed on microsubs. At the National Oceanography Centre in Southampton, we have developed a new miniaturised methane sensor that could be deployed on microsubs. In this project, we will adapt this sensor to be deployed on ecoSUB, a microsub developed at the NOC in partnership with Planet Ocean. We will work with BP to test the ecoSUB equipped with the methane sensor on demonstration missions, and help BP to change the way in which they perform leak detection and exploration. Detecting leaks early using microsubs will help BP reduce the cost and environmental impact of subsea pipeline leaks. More efficient exploration will reduce the cost environmental impact of searching for new oil and gas reserves.

Autonomous Underwater Vehicles (AUVs) can be loaded with chemical sensors and sent on missions to conduct high-resolution surveys in the deep sea. They are of interest to the oil and gas industry, as, if fitted with the right sensors, they can be used to help monitor subsea pipelines for leaks and also pinpoint new hydrocarbon reserves under the seafloor by measuring the chemical composition (e.g. the dissolved methane concentration) of the waters above. However, AUVs are prohibitively expensive for routine monitoring and exploration, and often require a large and expensive ship to be present on the surface. A new innovation in AUV technology is the microsub. These miniature AUVs can cost about 2% of the price of a traditional large AUV and are small enough to be launched from a small inflatable boat or the shoreline. They can reach complex areas (shallow waters and reefs) that larger AUVs cannot get to, and can operate in large swarms to efficiently survey a large area. The main drawback of microsubs is that they have limited onboard space and power, meaning that many sensor systems cannot be carried. This means the measurements performed by microsubs are very basic. No methane sensors are currently available that can be deployed on microsubs. At the National Oceanography Centre in Southampton, we have developed a new miniaturised methane sensor that could be deployed on microsubs. In this project, we will adapt this sensor to be deployed on ecoSUB, a microsub developed at the NOC in partnership with Planet Ocean. We will work with BP to test the ecoSUB equipped with the methane sensor on demonstration missions, and help BP to change the way in which they perform leak detection and exploration. Detecting leaks early using microsubs will help BP reduce the cost and environmental impact of subsea pipeline leaks. More efficient exploration will reduce the cost environmental impact of searching for new oil and gas reserves.