Electrical energy storage can contribute to meeting the UK's binding greenhouse emission targets by enabling low carbon transport through electric vehicles (EVs) in the expanding electric automotive industry. However, challenges persist in terms of performance, safety, durability and costs of the energy storage devices such as lithium ion batteries (LIBs). Although there has been research in developing new chemistry and advanced materials that has significantly improved electrical energy storage performance, the structure of the electrodes and LIBs and their manufacturing methods have not been changed since the 1980s. The current manufacturing methods do not allow control over the structures at the electrode and device levels, which leads to restricted ion transport during cycling. The approach of this research is to develop a complete materials-manufacture-characterisation chain for LIBs, solid-state LIBs (SSLIBs) and next generation of batteries. Novel structures at the electrode and device levels will be designed to promote fast directional ion transport, increase energy and power densities, improve safety and cycling performance and reduce costs. New, scalable manufacturing techniques will be developed to realise making the designed structures and reduce interfacial resistance in SSLIBs. Finally, state-of-the-art physical and chemical characterisation techniques including a suite of X-ray photoelectron spectroscopy (XPS), X-ray computed tomography (XCT) and electrochemical testing will be used to understand the underlining charge storage mechanism, interfacial phenomena and how electrochemical performance is influenced by structural changes of the energy storage devices. The results will subsequently be used to guide iterations of the structure design. The fabricated batteries will be packaged into pouch cells and rigorously tested by EV protocols through close collaborations with industry to ensure flexible adaptability to the current industry match to create near-term high impact in industry. The commercialisation strategy is to license developed intellectual property (IP) to material and battery manufacturers.

As recently as the 9th November 2012, the UK Chancellor, Mr George Osborne, stated in a speech to the Royal Society that "there is the challenge of storing more electricity for the Grid. Electricity demand peaks at around 60GW, whilst we have a grid capacity of around 80GW - but storage capacity of around just 3GW. Greater capability to store electricity is crucial for these power sources to be viable. It promises savings on UK energy spend of up to £10 billion a year by 2050 as extra capacity for peak load is less necessary." China, by contrast, has a grid capacity of over 1,000GW and an electrical demand growth rate of over 11% p.a, and in 2011 installed more wind capacity than the rest of the world put together. Concurrently, plans to clean up emissions from the transport sectors are leading to ambitious plans to expand the use of electric vehicles which will both challenge the electricity system due to the substantial need for battery charging, but also provide opportunity as these batteries can be used to provide energy storage. Hence the challenge for both the UK and China is, recognising the current global EV market is forecast to grow from 1.7 million units in 2012 to 5.3 million units in 2020, how to utilise this massive aggregate electrical energy storage capacity from EV batteries to deliver essential power network services such as frequency support, load levelling, 'firming' of renewable generation and so forth. The dual use of such vehicle energy storage (to provide its core vehicle transportation duty and grid support when connected to the network for recharging) is referred to as Vehicle-to-Grid (V2G) operation. V2G has many technical challenges to overcome as well as requiring careful cost benefit analysis of the effect of increased charge/discharge cycling of the battery, and associated degradation, versus the grid support benefits achieved. The dual use of EV batteries to provide grid support will make available very fast acting (<5 sec) and, crucially, low cost (Euro22/kW) aggregated energy storage, at cost levels significantly below dedicated grid battery installations (e.g. Euro3180/kW (@$1=Euro0.75) for the PGE 5MW, 1.25MWh Li-ion battery grid support project in Salem, Oregon, US) or competing energy storage technologies like compressed air energy storage (CAES). Critically this proposal aims to focus on V2G operation from a battery perspective 'upwards' and not from a network level 'downwards', as the key factors relating to the success of V2G are those concerned with the battery technology. The research challenges identified with this work are: 1) Determining the anticipated patterns of battery cycling associated with driving and V2G operation for specified grid support functions e.g. frequency support, peak shaving etc. 2) Investigating the impact of the anticipated V2G operation on battery cell, module and pack cycle life, failures and thermal behaviour (i.e. thermal cycling and impact on cold/hot battery charging behaviour). Additionally more accurate determination of battery state of charge (SoC) and state of health (SoH) is required, including ensuring cell balance within the battery pack. 3) Investigating the communication and control temporal and physical information requirements from the battery management system (BMS) to the grid control system and vice versa. 4) Demonstrating V2G operation within distinct UK and Chinese environments, employing the new BMS software with cycling/thermal control, and improved SoC/SoH prediction.

The ability to store and release energy on demand is essential to an energy future that is based on clean, non-polluting and sustainable renewable energy. This includes both electrical and thermal energy and a large number of technologies are being developed to fulfil this need. Energy storage will become a major industry in our century and will employ hundreds of thousands of people globally. Energy storage will be everywhere - in large scale batteries connected to electrical networks, in homes to store energy generated from solar panels and in cars, replacing petrol engines. In order to meet this challenge and to ensure that UK plays an important role in this industry we will form a Centre of Doctoral Training in to train researchers at the highest level to help form and influence the direction of Energy Storage technologies. Our students will receive training in all aspects of energy but concentrating on the core technologies of electrochemical storage (batteries and supercapacitors), mechanical storage, thermal storage and superconducting magnetic energy storage. They will have the opportunity to interact with industrialists and gain experience in running a grid connected Lithium-ion battery. They will also undertake a major three-year research project allowing them to specialise in the topic of their choice.

High-performance batteries had disruptive impact in the electronics sector, are pivotal in electrifying transport, and will play a crucial role in grid-scale storage solutions. In particular, Li-Ion and Na-Ion batteries are set to facilitate greater and more efficient use of renewable energy. Application demand for highest possible energy density and power, however, necessitates volatile chemistries and careful consideration of safety aspects as a number of high-profile battery accidents have made strikingly clear in recent years. The most catastrophic failure of Li-ion battery systems is a cascading thermal runaway. Thermal runaway can occur due to thermal, electrical, or mechanical abuse. It can result in the venting of toxic and highly flammable gases and the release of significant heat, potentially leading to explosions and severe damage to the battery, surrounding equipment and/or people. This project will provide materials technologies to physically safeguard Li-Ion and Na-Ion batteries against thermal runaway and thermally accelerated degradation, superseding existing external safety measures. Rather than changing the active material on the positive side, we will replace conductivity additives, an otherwise passive component of the electrodes, with smart materials. Electrical resistivity of the smart additives will increase by orders of magnitude at or above temperatures where it would otherwise be unsafe to operate the battery. As a consequence, uncontrolled electrochemical reactions, the initial heat source in a thermal runaway event, will cease, making electrochemically initiated thermal runaway impossible. The approach has several advantages: (1) it provides a drop-in solution, applicable to all active material chemistries in Li-Ion and Na-Ion batteries; (2) it is transferable to other battery technologies (e.g, Al-Ion); (3) it safeguards against a full range of abuse scenarios triggering thermal runaway; and (4) the protection mechanisms will be reversible with lifetime benefits of batteries under real-world situations. Smart additives will be developed utilising rational materials design driven by close integration between simulations at the atomistic and micro-scale with a comprehensive synthesis and characterisation program including a full array of in operando advanced electrochemical/spectroscopic techniques and x-ray tomography, complemented by state-of-the-art ex situ materials characterisation. Relevant abuse protocols will be developed and utilised to test batteries comprising electrodes with the smart additives at the cell and pack level. Further, we will exploit secondary characteristics of the smart additives to realise and demonstrate high-fidelity, non-invasive diagnostics and battery management to add an active safety layer for superior longevity. Alignment with ISCF objectives: Bringing together a complete value chain including SMIs (REAPsystems, Denchi), tier 1+2 suppliers (Johnson Matthey, Faradion, Yuasa), and larger OEMs (QinetiQ, Lloyd's, Dstl) with leading academics from engineering and chemistry (objectives 3+4), this project will innovate to deliver safer battery technologies and associated IP for automotive and other applications, increasing the UKs attractiveness for inward investment (objective 5) from global automotive OEMs and suppliers. Leveraged with over £150k support from industry, the program will increase the UKs R&D capacity/capability in battery research and deliver a world-leading, multi-disciplinary research program (objective 1) that is perfectly aligned with the 'Faraday Challenge' objectives, a UK flagship investment to develop and manufacture batteries for the electrification of vehicles (objective 2).

Electrical energy storage can contribute to meeting the UK's binding greenhouse emission targets by enabling low carbon transport through electric vehicles (EVs) in the expanding electric automotive industry. However, challenges persist in terms of performance, safety, durability and costs of the energy storage devices such as lithium ion batteries (LIBs). Although there has been research in developing new chemistry and advanced materials that has significantly improved electrical energy storage performance, the structure of the electrodes and LIBs and their manufacturing methods have not been changed since the 1980s. The current manufacturing methods do not allow control over the structures at the electrode and device levels, which leads to restricted ion transport during cycling. The approach of this research is to develop a complete materials-manufacture-characterisation chain for LIBs, solid-state LIBs (SSLIBs) and next generation of batteries. Novel structures at the electrode and device levels will be designed to promote fast directional ion transport, increase energy and power densities, improve safety and cycling performance and reduce costs. New, scalable manufacturing techniques will be developed to realise making the designed structures and reduce interfacial resistance in SSLIBs. Finally, state-of-the-art physical and chemical characterisation techniques including a suite of X-ray photoelectron spectroscopy (XPS), X-ray computed tomography (XCT) and electrochemical testing will be used to understand the underlining charge storage mechanism, interfacial phenomena and how electrochemical performance is influenced by structural changes of the energy storage devices. The results will subsequently be used to guide iterations of the structure design. The fabricated batteries will be packaged into pouch cells and rigorously tested by EV protocols through close collaborations with industry to ensure flexible adaptability to the current industry match to create near-term high impact in industry. The commercialisation strategy is to license developed intellectual property (IP) to material and battery manufacturers.