The purpose of this proposal is to create a water-based reversible adhesive using commodity materials that is inexpensive, scalable, and environmentally friendly. The target impact of this research is a commercially successful adhesive that has widespread applications, particularly in areas where recycling is important, such as bottle labelling. Other areas, such as automotive parts and e-waste management, would also benefit by supporting a design for an environment approach in which, at the end of the first life cycle, products can be dismantled, and parts repurposed. The technology can also function as a simple water-based adhesive to replace other glues based on volatile organic compounds. The premise is simple: a surface coated with a positively charged polymer can adhere to one coated with a negatively charged polymer. These will stick in water and remain adhered even after the contact has dried. Changing the local pH changes the charge on the polyelectrolytes so that, in an acid pH, the polyacid will become neutral. The polybase will remain charged and the adhesion fails. Previous demonstrations of reversible adhesion have required the end-user to perform significant chemistry. Here we are proposing a simple route to reversible adhesion based on a standard polymerization process. The surfaces to be adhered would each be coated by separate layers and joined. Adhesion is expected to be instantaneous and durable. Unlike other water-based adhesives, exposure to moisture would not compromise the joint. An acid or alkaline wash would be used to separate the two components. A rapid and effective means of disjoining requires significant research and forms a large part of this proposal. In addition, the spray coating of polyelectrolytes onto surfaces will also be explored as a simple route to adhesion for a limited range of applications. The technology will be validated in collaboration with partner companies.

Industry is responsible for 25% of carbon dioxide emissions from the European Union with around 60% of these emissions coming from the energy-intensive chemical, petrol refining, cement, steel and cement industries. The products of these process plants are fundamental to the global economy however many of the corresponding manufacturing processes are operating at (or are close to) their maximum practical efficiency. This reduces the impact of any future efficiency improvement measures in reducing overall carbon dioxide emissions across the sector. Industrial Carbon Capture and Storage (ICCS) is considered by the International Energy Agency (IEA) as the "most important technology" to decarbonise the industrial sector. This technology couples into industrial process plants, separates out the carbon dioxide and transports it to a suitable location for long term underground storage. In this way, the process plants are no longer venting unwanted carbon dioxide emissions directly into the atmosphere. Whilst many of the key components in ICCS have been demonstrated in pilot scale projects, the deployment of a full scale system remains a challenge due to the high capital costs associated with developing the infrastructure for carbon dioxide capture, transportation and storage. One effective means to address these issues is to share the burden by developing regional clusters of industrial process plants which all feed into a common ICCS network. This project brings together a strong academic team from Newcastle University, Imperial College and Cambridge University with significant technical support from the International Energy Agency, industrial technical experts, various CCS clusters and demonstration sites. The project will be the first of its kind to evaluate multiple potential ICCS clusters planned worldwide and assess their impact on products and consumers. It will mainly focus on a cluster planned in Teesside, UK featuring a steel furnace, ammonia manufacturing site, a hydrogen reforming facility, and a chemical plant. It will collate technical data from many of the pilot demonstrations in the United States and Europe to gain a more comprehensive understanding of the required operation of other relevant energy intensive process plants such as petroleum refineries and cement production sites. This technical data will be used to develop a set of software design tools for the planning of ICCS clusters and develop a means to optimise their operation. In addition, a robust set of economic analysis tools will be developed to support evaluation of the economics and costs associated with the technology. The impact on the supply chain will be assessed through a comprehensive outreach and public engagement exercise. Ideas for new low-carbon products will be developed and their costs evaluated. This process will include surveys and focus groups to gain opinions and data from key stakeholders who operate in the supply chains of planned ICCS clusters. This will include regular communication with business-to-business customers right through to end-users and consumers. This will be used to gain a greater understanding of attitudes towards these potential lower-carbon products and to assess the strength of consumer pull under multiple carbon pricing/policy scenarios.

Abstracts are not currently available in GtR for all funded research. This is normally because the abstract was not required at the time of proposal submission, but may be because it included sensitive information such as personal details.

Abstracts are not currently available in GtR for all funded research. This is normally because the abstract was not required at the time of proposal submission, but may be because it included sensitive information such as personal details.

This research project addresses the process industry contribution to the UK government goals of tackling climate change and reducing dependence on imported fuel. This programme fills these nationally important objectives by investigating the short, medium and long-term provision of energy for the UK, based on thermal technologies that exploit low grade process heat that is currently not recovered by this industry. The results of this 'Whole Systems Analysis research will improve plant efficiency and displace a significant fraction of fossil fuel use, thus reducing UK carbon dioxide emissions, by using techniques that are secure, clean, affordable and socially welcome. This research involves collaboration between several highly relevant industrial partners (e.g. Corus Ltd, North East Process Industry Cluster (NEPIC) Ltd, EON UK, Veolia (Sheffield Heat & Power Ltd), Pfizer Ltd, etc) and four internationally leading academic centres of excellence (Universities of Sheffield, Newcastle, Manchester & Tyndall Centre). The research programme targets a national problem by exploiting their complementary expertise through Whole Systems Analysis . Thus the objective of this research proposal is to investigate new and appropriate technologies and strategies needed for industry to exploit the large amount of unused low grade heat available. This will be achieved by providing a systematic procedure based on a comprehensive analysis of all aspects of process viability that will enable industry to optimise the management and exploitation of their thermal energy. This detailed procedure will be backed up by a sustained channel of communication between the relevant industrial and academic parties. This multidisciplinary work is thus applicable both to existing plants and the design of future plants. Please note that the establishment of an associated but separately funded EPSRC Network (e.g. PRO-TEM) is considered to be an integral part of this project, in order to satisfy the implicit role of technology transfer in both directions, between the process industry and the wider academic community. It will also provide access to industrial players who will provide essential case studies for the technical and socio-economic work. The case for an associated PRO-TEM Network is briefly discussed herein and the case is presented in detail in a separate proposal by Newcastle University.