Energy demand is growing and our society faces a challenge to find sustainable sources with minimal environmental impact. Existing technologies such as solar, wind and geothermal have been deployed and effort to improve their physical and cost effectiveness is ongoing. Another source of renewable energy available which has not been harvested to its full potential so far is "waste" heat. It arises from a variety of sources, from household boiler to large scale power plant, and a striking example is the conventional combustion engine in which 60 % of the energy produced is lost in the form of heat. The possibility to design a semiconductor device made of p-n junctions which when exposed to a temperature gradient will output electrical power is an attractive solution for the automotive industry to improve fuel efficiency, lower the carbon foot print and end-user costs. This device, called a thermoelectric generator has been successfully used for aero-spatial application or in its converse form as Peltier cooler, contributes to all component of the energy trilemma. The major barrier for a widespread dissemination of this technology as energy harvester is the high raw material costs and a lack of material for high temperature operation. This research will investigate new classes of inorganic oxide composed of earth abundant elements presenting electrical and thermal properties suitable for integration in a high temperature thermoelectric generator. Efficient thermoelectric materials possess high electrical conductivity and low thermal conductivity which, in a standard semiconductor picture, are antagonistic properties. Focusing on the high temperature spectrum, oxides materials will display the chemical stability required for the device to function reliably. Since the majority of these materials are electrically insulating, the concept is based on identifying structure patterns that have hidden electronic lattice which could act as conducting channel. Similar concept has been successfully applied on layered oxides where only competitive p-type thermoelectric materials where produced. The project aims to explore the possibility to use the strong correlation between electronic, thermal and magnetic lattice to circumvent the limitations encountered in this class of materials and expand our understanding of this complex compounds. A specific objective of the project is to prepare poly- and single crystalline layered oxides derived from the trirutile structure, measure the high temperature conductivity and thermopower and optimise the thermoelectric property using chemical doping to obtain both p and n type compounds. The layered structures of the proposed compounds are conducive to exotic magnetic properties and more complex phenomena such as Nernst-Ettinghausen effect and spin Seebeck effect will be investigated.

Manufacture Using Advanced Powder Processes - MAPP Conventional materials shaping and processing are hugely wasteful and energy intensive. Even with well-structured materials circulation strategies in place to recondition and recycle process scrap, the energy use, CO2 emitted and financial costs associated are ever more prohibitive and unacceptable. We can no longer accept the traditional paradigm of manufacturing where excess energy use and high levels of recycling / down cycling of expensive and resource intensive materials are viewed as inevitable and the norm and must move to a situation where 100% of the starting material is incorporated into engineering products with high confidence in the final critical properties. MAPP's vision is to deliver on the promise of powder-based manufacturing processes to provide low energy, low cost, and low waste high value manufacturing route and products to secure UK manufacturing productivity and growth. MAPP will deliver on the promise of advanced powder processing technologies through creation of new, connected, intelligent, cyber-physical manufacturing environments to achieve 'right first time' product manufacture. Achieving our vision and realising the potential of these technologies will enable us to meet our societal goals of reducing energy consumption, materials use, and CO2 emissions, and our economic goals of increasing productivity, rebalancing the UK's economy, and driving economic growth and wealth creation. We have developed a clear strategy with a collaborative and interdisciplinary research and innovation programme that focuses our collective efforts to deliver new understanding, actions and outcomes across the following themes: 1) Particulate science and innovation. Powders will become active and designed rather than passive elements in their processing. Control of surface state, surface chemistry, structure, bulk chemistry, morphologies and size will result in particles designed for process efficiency / reliability and product performance. Surface control will enable us to protect particles out of process and activate them within. Understanding the influence between particle attributes and processing will widen the limited palette of materials for both current and future manufacturing platforms. 2) Integrated process monitoring, modelling and control technologies. New approaches to powder processing will allow us to handle the inherent variability of particulates and their stochastic behaviours. Insights from advanced in-situ characterisation will enable the development of new monitoring technologies that assure quality, and coupled to modelling approaches allow optimisation and control. Data streaming and processing for adaptive and predictive real-time control will be integral in future manufacturing platforms increasing productivity and confidence. 3) Sustainable and future manufacturing technologies. Our approach will deliver certainty and integrity with final products at net or near net shape with reduced scrap, lower energy use, and lower CO2 emissions. Recoupling the materials science with the manufacturing science will allow us to realise the potential of current technologies and develop new home-grown manufacturing processes, to secure the prosperity of UK industry. MAPP's focused and collaborative research agenda covers emerging powder based manufacturing technologies: spark plasma sintering (SPS), freeze casting, inkjet printing, layer-by-layer manufacture, hot isostatic pressing (HIP), and laser, electron beam, and indirect additive manufacturing (AM). MAPP covers a wide range of engineering materials where powder processing has the clear potential to drive disruptive growth - including advanced ceramics, polymers, metals, with our initial applications in aerospace and energy sectors - but where common problems must be addressed.

The Transforming the Foundation Industries Challenge has set out the background of the six foundation industries; cement, ceramics, chemicals, glass, metals and paper, which produce 28 Mt pa (75% of all materials in our economy) with a value of £52Bn but also create 10% of UK CO2 emissions. These materials industries are the root of all supply chains providing fundamental products into the industrial sector, often in vertically-integrated fashion. They have a number of common factors: they are water, resource and energy-intensive, often needing high temperature processing; they share processes such as grinding, heating and cooling; they produce high-volume, often pernicious waste streams, including heat; and they have low profit margins, making them vulnerable to energy cost changes and to foreign competition. Our Vision is to build a proactive, multidisciplinary research and practice driven Research and Innovation Hub that optimises the flows of all resources within and between the FIs. The Hub will work with communities where the industries are located to assist the UK in achieving its Net Zero 2050 targets, and transform these industries into modern manufactories which are non-polluting, resource efficient and attractive places to be employed. TransFIRe is a consortium of 20 investigators from 12 institutions, 49 companies and 14 NGO and government organisations related to the sectors, with expertise across the FIs as well as energy mapping, life cycle and sustainability, industrial symbiosis, computer science, AI and digital manufacturing, management, social science and technology transfer. TransFIRe will initially focus on three major challenges: 1 Transferring best practice - applying "Gentani": Across the FIs there are many processes that are similar, e.g. comminution, granulation, drying, cooling, heat exchange, materials transportation and handling. Using the philosophy Gentani (minimum resource needed to carry out a process) this research would benchmark and identify best practices considering resource efficiencies (energy, water etc.) and environmental impacts (dust, emissions etc.) across sectors and share information horizontally. 2 Where there's muck there's brass - creating new materials and process opportunities. Key to the transformation of our Foundation Industries will be development of smart, new materials and processes that enable cheaper, lower-energy and lower-carbon products. Through supporting a combination of fundamental research and focused technology development, the Hub will directly address these needs. For example, all sectors have material waste streams that could be used as raw materials for other sectors in the industrial landscape with little or no further processing. There is great potential to add more value by "upcycling" waste by further processes to develop new materials and alternative by-products from innovative processing technologies with less environmental impact. This requires novel industrial symbioses and relationships, sustainable and circular business models and governance arrangements. 3 Working with communities - co-development of new business and social enterprises. Large volumes of warm air and water are produced across the sectors, providing opportunities for low grade energy capture. Collaboratively with communities around FIs, we will identify the potential for co-located initiatives (district heating, market gardening etc.). This research will highlight issues of equality, diversity and inclusiveness, investigating the potential from societal, environmental, technical, business and governance perspectives. Added value to the project comes from the £3.5 M in-kind support of materials and equipment and use of manufacturing sites for real-life testing as well as a number of linked and aligned PhDs/EngDs from HEIs and partners This in-kind support will offer even greater return on investment and strongly embed the findings and operationalise them within the sector.

This proposal is a Platform Grant renewal. Our previous grant allowed us to develop the key characterisation facilities and enabled us to understand fully the materials that were the study of the grant. These materials were low loss microwave dielectrics, ferroelectric materials and thin films of these materials. The Platform renewal will build upon some remarkable discoveries that the team, including the key PDRAs, has made over the last 4 years and centre around functional materials for devices operating from microwave to millimetre wave or from MHz to THz. First it is important to explain the Materials Science progress that forms the underpinning technologies that will enable us to use the Platform grant to build new devices. At the heart of microwave devices are resonators that require low dielectric loss or very high Q factor and the target is to aim for very high Q dielectrics. Our previous Platform grant and indeed prior support from EPSRC allowed us to discover very low loss, high Q materials. This culminated in two significant discoveries. 1 First we were able to use low loss resonators as sensors for liquid sensing 2 Second, we demonstrated that by using a very high Q resonator we could achieve maser action at room temperature and in Earth's field - published in Nature 2012. This platform grant will enable us to build upon these discoveries. 1) Advanced Characterisation: In the first theme the aim will be to carry out a series of qualifying experiments to determine the best possible conditions and materials for sensing over the wide range of frequencies available to us (Hz to THz) 2) Microwave and mm wave sensors: The third theme takes the science to application. We will use the resonators for analysis of ions, biomolecules, proteins and cells. The sensitivity of the resonators allows nanolitre quantities to be analyzed very rapidly for possible cancer cell detection in blood and bacteria in water. 3) "UMPF" and "HEP" Cavities: In the second theme we aim to make UMPF (Ultrahigh Magnetic Purcell Factor) and "HEP" (High Electric Purcell) cavities. These are small resonant cavities with a very high Q given the very small mode volume and success here will enable us to improve electron paramagnetic sensing dramatically and enable single cell detection. Success in these new themes for the Platform would represent a remarkable step-change in technology.

Ceramic materials are used in a wide range of applications including motion sensors, for energy storage in electric vehicles, dental replacement, hip and knee implants, cutting blades, and body and vehicle armour. They are exceptionally durable, even at high temperatures and in corrosive environments, and can be reused or recycled at the end of their life. However the high cost of manufacturing is a major barrier to the use of ceramic materials. Producing a dense strong ceramic material with minimal porosity requires heating to very high temperatures well over 1000 deg.C typically for many hours. Recently scientists have discovered that the temperature and duration of the ceramic densification process (sintering) can be significantly reduced by passing an electric field through the ceramic during the heating process. This "flash sintering" process, so-called because the material densifies extremely rapidly within a few seconds and often with the simultaneous emission of light, has potential to significantly reduce energy use in industrial-scale ceramic manufacturing and reduce emissions of greenhouse gases from the process by up to 40%. The flash sintering technique may revolutionise the ceramic manufacturing industry by reducing the cost and environmental impact of producing ceramic materials. In this research project a detailed investigation of the flash sintering method will be undertaken to establish the viability of this technique for use with a wide range of ceramic materials and particularly to understand the underlying mechanisms which cause the flash sintering effect. A flexible flash sintering facility will be established which can be used to flash sinter a wide range of ceramic materials. Composite materials with varying electrical conductivity will be flash sintered under different conditions. The results will used to understand the effect of both the material properties and the variables involved in the process (e.g. electric field strength, current, voltage, and temperature) on the observed flash sintering behaviour. Materials will be characterised by measuring their density, imaging using scanning electron microscopy and mapping the chemical composition, and using X-ray diffraction to determine any changes to the phase composition of the materials caused by the flash sintering process. New insights will be gained by flash sintering for the first time a structure made of layers of ceramic composite materials graded by composition and examining how the flash sintering behaviour changes compared to samples containing each individual composition. The results of this project will be used by our industrial project partners Lucideon and Morgan Advanced Materials in the industrial development and application of flash sintering technology.